I have. I used it to make the sky in this cake... http://www.cakecentral.com/modules.php?name=gallery&file=displayimage&pid=1300118 I only have the blue wilton color mist and I've only used it twice though.
I have used the pink and purple color mist on this cupcake cake. Simple to use.
http://cakecentral.com/modules.php?name=gallery&file=displayimage&pid=20277
I've used it. And I cleaned red overspray off my whole kitchen after spraying just one cake. It would be a good idea to create a protected spray area (like inside a big box) because there is a lot of overspray.
The box I used had no top and was cut down on two corners so that one side was down flat on the table. This gives you 3 high walls and a floor with a flap out front. Place your cake on a turntable inside the box so you can turn and spray at the same time. Put newspapers down all around the box too.
I used the black on my chalkboard cake (in my pics, don't know how to link) and it worked great but I agree about overspray. I did it outside
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